It depends on what model you're planning on using the Hawk Turquoise on. If it's a model like an Eldar Swooping Hawk, then a white undercoat would be good, as these guys tend to be very "in your face" with bright colours. If it's on a Space Marine, then black is better as they are not really renowned for gaudy colours (unless they're Slaaneshi Noise Marines!)
As for highlighting the colour itself, those colours already mentioned will give you different results, so it would be worth your while to check out each one to find which you are happiest with for what you want for your model.
E.
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