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Honestly? Orange and brown will give you a very muddy looking army. Look at a colour wheel or find a website that will give you complimentary colours to find a better match for orange or another scheme altogether even.
I agree with Muse, the colours are too similar. The orange would look good but I suggest changing the brown to a lighter colour maybe a light grey or white. Just something to separate the colours.
In effect what you have on these soldiers is heraldry and it's worth following the same rules that medieval heralds would have used. Colours were split into two sets, white and yellow were 'metals' and blue, red, purple, black and green were 'colours'. A colour can never touch a colour and a metal can never touch a metal so as to maintain some contrast.
As you are not using traditional colours you can't stick to that directly, but as the other posters have said, a colour wheel could help. By using orange your army will look modern, but you can get a decent contrast and avoid, as Muse quite neatly described, a muddy look.
I use orange as a spot colour on my mainly blue and grey army, it's opposite glue on a colour wheel so contrasts well. You could have orange cloth, with blue details, as that is a complimentary colour, with grey armour, which as a neutral colour won't dominate either colour.
I think it could work, but the orange would have to be very strong and quite bright to work alongside the brown. If you are not careful, as pointed out earlier it could turn very muddy.
Thank you guys for all the help, i have since decided to go with a different paint scheme, but i will keep your advice in mind
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