I'm a demons player and got to say, though the main opinion is "Demons are too random to be competitive", I' won quite alot in the one tournament I played. They're a fun army to play too - funnest I've played. The flugg isn't all that bad either.
Out of the armies I've faced, SM was by far the easiest to kill. Haven't faced new IG yet, but the new codex looks awesome. Orks I had some trouble with - a giant swarm of orks HURTS on all armies to be honest. Crons are pretty good too - WBB rolls are awesome, but you tend to see lots of power weapons around.
Haven't ever faced Dark Eldar with any of my armies, so can't comment on that - nobody even knows how they are on paper here.
Eldar I found some pretty hard opponents - their normal weapons are assault 2, so it's basically a rapidfiring bolter but with a bigger range etc. D-Cannons, Vibro Cannons and similiar weapons hurt - lots of eldar weaponry actually do a lot against vehicles - many glance on a 3 or 4, penetrate on a 5 or 6, which on a landraider is better than a krak missile can do (by far)